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Would there ever be a scenario, for example where piece A would have a lower Ecopoint value than piece B, but a higher carbon score? Which should we give the greater attention to – Ecopoints or kg of carbon?

Yes, that could be possible. The results of the carbon score are included in the overall Ecopoint score (as it is represented in the Climate Change impact). It preferable to consider the Ecopoint score over the carbon score.